A. Same in both the phases
B. Zero in both the phases
C. More in vapour phase
D. More in liquid phase
Related Mcqs:
- A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yi is the liquid activity coefficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of ______________________?
A. Temperature only
B. Temperature and pressure only
C. Temperature, pressure and liquid composition xi only
D. Temperature, pressure, liquid composition xi and vapour composition yi - At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.) ?
A. μ° + RT ln f
B. μ°+ R ln f
C. μ° + T ln f
D. μ° + R/T ln f - Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance at constant temperature and pressure is________________?
A. 0
B. 1
C. ∞
D. None of these - At 60° C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An aqueous solution of methanol at 60° C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase mole fractions of methanol are 0.1686 and 0.5714 respectively. Activity co-efficient of methanol is__________________?
A. 1.572
B. 1.9398
C. 3.389
D. 4.238 - Saturated solution of benzene in water is in equilibrium with a mixture of air and vapours of benzene and water at room temperature and pressure. Mole fraction of benzene in liquid is xB and the vapour pressures of benzene and water at these conditions are pv B and pv w respectively. The partial pressure of benzene in air-vapour mixture is_________________?
A. PvB
B. xB.PvB
C. (Patm – Pvw)xB
D. xB.Patm - When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is__________________?
A. More in vapour phase
B. More in liquid phase
C. Same in both the phases
D. Replaced by chemical potential which is more in vapour phase - For water at 300°C, it has a vapour pressure 8592.7 kPa and fugacity 6738.9 kPa Under these conditions, one mole of water in liquid phase has a volume of 25.28 cm3 and that in vapour phase in 391.1 cm3.Fugacity of water (in kPa) at 9000 kPa will be__________________?
A. 6738.9
B. 6753.5
C. 7058.3
D. 9000 - For multi-component multiple phases to be in equilibrium at the same pressure and temperature, the _______________ of each component must be same in all phases?
A. Chemical potential
B. Fugacity
C. Both A. and B
D. Neither A. nor B - The chemical potential of a component (μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of substance added for an infinitesimal addition at constant temperature and pressure. It is given by_________________?
A. (∂E/∂ni)S, v, nj
B. (∂G/∂ni)T, P, nj = (∂A/∂ni) T, v, nj
C. (∂H/∂ni)S, P, nj
D. All (A), B. and (C) - The vapour pressure of water is given by, in Psat = A – (5000/T), where A is a constant, Psat is the vapour pressure in atm. and T is the temperature in K. The vapor pressure of water in atm. at 50°C is approximately__________________?
A. 0.07
B. 0.09
C. 0.11
D. 0.13
