For multi-component multiple phases to be in equilibrium at the same pressure and temperature, the _______________ of each component must be same in all phases?

Related Mcqs:

1. When liquid and vapour phase of multi-component system are in equilibrium (at a given temperature and pressure), then chemical potential of each component is___________________?

   A. Same in both the phases
   B. Zero in both the phases
   C. More in vapour phase
   D. More in liquid phase

2. Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and temperature ____________ as its mole fraction increases?

   A. Decreases
   B. Decreases exponentially
   C. Increases
   D. Remain constant

3. When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is__________________?

   A. More in vapour phase
   B. More in liquid phase
   C. Same in both the phases
   D. Replaced by chemical potential which is more in vapour phase

4. Variation of equilibrium pressure with temperature for any two phases of a given substances is given by the ____________ equation?

   A. Gibbs-Duhem
   B. Maxwell’s
   C. Clapeyron
   D. None of these

5. A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yi is the liquid activity coefficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of ______________________?

   A. Temperature only
   B. Temperature and pressure only
   C. Temperature, pressure and liquid composition xi only
   D. Temperature, pressure, liquid composition xi and vapour composition yi

6. Consider the equilibrium A(g) + B(g) = AB(g). When the partial pressure of A is 10-2 atm, the partial pressure of B is 10-3 atm and the partial pressure of AB is 1 atm, the equilibrium constant ‘K’ is____________________?

   A. 10 atm-1
   B. 105 atm-1
   C. 10 (dimensionless)
   D. 105 (dimensionless)

7. The reaction A (l) → R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The numbers of degrees of freedom are ?

   A. 1
   B. 2
   C. 3
   D. 0

8. The equilibrium data of component A in the two phases B and C are given below. The estimate of Y for X = 4 by fitting a quadratic expression of a form Y = mX2 for the above data is ____________________?

   A. 15.5
   B. 16
   C. 16.5
   D. 17

9. “When a system in equilibrium is subjected to a change in temperature, pressure or concentration, the equilibrium is displaced in a direction which tends to undo the effect of the change.” This is called the_______________?

   A. Le-Chatelier principle
   B. Kopp’s rule
   C. Law of corresponding state
   D. Arrhenius hypothesis

10. Saturated solution of benzene in water is in equilibrium with a mixture of air and vapours of benzene and water at room temperature and pressure. Mole fraction of benzene in liquid is xB and the vapour pressures of benzene and water at these conditions are pv B and pv w respectively. The partial pressure of benzene in air-vapour mixture is_________________?

    A. PvB
    B. xB.PvB
    C. (Patm – Pvw)xB
    D. xB.Patm