A. More in vapour phase
B. More in liquid phase
C. Same in both the phases
D. Replaced by chemical potential which is more in vapour phase
Related Mcqs:
- For multi-component multiple phases to be in equilibrium at the same pressure and temperature, the _______________ of each component must be same in all phases?
A. Chemical potential
B. Fugacity
C. Both A. and B
D. Neither A. nor B - When liquid and vapour phase of multi-component system are in equilibrium (at a given temperature and pressure), then chemical potential of each component is___________________?
A. Same in both the phases
B. Zero in both the phases
C. More in vapour phase
D. More in liquid phase - A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yi is the liquid activity coefficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of ______________________?
A. Temperature only
B. Temperature and pressure only
C. Temperature, pressure and liquid composition xi only
D. Temperature, pressure, liquid composition xi and vapour composition yi - The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1 is the activity co-efficient of component 1, is__________________?
A. A . x22
B. Ax1
C. Ax2
D. Ax12 - Saturated solution of benzene in water is in equilibrium with a mixture of air and vapours of benzene and water at room temperature and pressure. Mole fraction of benzene in liquid is xB and the vapour pressures of benzene and water at these conditions are pv B and pv w respectively. The partial pressure of benzene in air-vapour mixture is_________________?
A. PvB
B. xB.PvB
C. (Patm – Pvw)xB
D. xB.Patm - The vapour pressure of water is given by, in Psat = A – (5000/T), where A is a constant, Psat is the vapour pressure in atm. and T is the temperature in K. The vapor pressure of water in atm. at 50°C is approximately__________________?
A. 0.07
B. 0.09
C. 0.11
D. 0.13 - At 60° C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An aqueous solution of methanol at 60° C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase mole fractions of methanol are 0.1686 and 0.5714 respectively. Activity co-efficient of methanol is__________________?
A. 1.572
B. 1.9398
C. 3.389
D. 4.238 - Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance at constant temperature and pressure is________________?
A. 0
B. 1
C. ∞
D. None of these - Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and temperature ____________ as its mole fraction increases?
A. Decreases
B. Decreases exponentially
C. Increases
D. Remain constant - Variation of equilibrium pressure with temperature for any two phases of a given substances is given by the ____________ equation?
A. Gibbs-Duhem
B. Maxwell’s
C. Clapeyron
D. None of these
