A. The concentration of each component should be same in the two phases
B. The temperature of each phase should be same
C. The pressure should be same in the two phases
D. The chemical potential of each component should be same in the two phases
Related Mcqs:
- For multi-component multiple phases to be in equilibrium at the same pressure and temperature, the _______________ of each component must be same in all phases?
A. Chemical potential
B. Fugacity
C. Both A. and B
D. Neither A. nor B - At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.) ?
A. μ° + RT ln f
B. μ°+ R ln f
C. μ° + T ln f
D. μ° + R/T ln f - The reaction A (l) → R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The numbers of degrees of freedom are ?
A. 1
B. 2
C. 3
D. 0 - For a thermodynamic system containing ‘x’ chemical species, the maximum number of phases that can co-exist at equilibrium is_________________?
A. x
B. x + 1
C. x + 2
D. x + 3 - The necessary condition for phase equilibrium in a multiphase system of N components is that the____________________?
A. Chemical potentials of a given component should be equal in all phases
B. Chemical potentials of all components should be same in a particular phase
C. Sum of the chemical potentials of any given component in all the phases should be the same
D. None of these - Solid and liquid phases of a substance are in equilibrium at the____________________?
A. Critical temperature
B. Melting point
C. Freezing point
D. Both B. and C - Variation of equilibrium pressure with temperature for any two phases of a given substances is given by the ____________ equation?
A. Gibbs-Duhem
B. Maxwell’s
C. Clapeyron
D. None of these - When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is__________________?
A. More in vapour phase
B. More in liquid phase
C. Same in both the phases
D. Replaced by chemical potential which is more in vapour phase - The equilibrium data of component A in the two phases B and C are given below. The estimate of Y for X = 4 by fitting a quadratic expression of a form Y = mX2 for the above data is ____________________?
A. 15.5
B. 16
C. 16.5
D. 17 - The molecules of a liquid which is in equilibrium with its vapor at its boiling point on an average have equal _____________ in the two phases?
A. Potential energy
B. Intermolecular forces
C. Kinetic energy
D. Total energy
