Which of the following holds good for a solution obeying Raoult’s law (i.e., an ideal solution) (where, ΔH = heat of mixing, and ΔV = volume change on mixing) ?

Related Mcqs:

1. Osmotic pressure of a dilute solution of a non volatile solute in a solvent obeying Raoult’s law is proportional to the_____________?

   A. Temperature
   B. Volume of solution
   C. Moles of non-volatile solute
   D. None of these

2. 80 kg of Na2SO4 (molecular weight = 142) is present in 330 kg of an aqueous solution. The solution is cooled such that. 80 kg of Na2SO4 .10H2O crystals separate out. The weight fraction of Na2SO4 in the remaining solution is_________________?

   A. 0.00
   B. 0.18
   C. 0.24
   D. 1.00

3. The activity co-efficient of a solution, which accounts for the departure of liquid phase from ideal solution behaviour________________?

   A. Measures the elevation in boiling point
   B. Is not dependent on the temperature
   C. Is a function of the liquid phase composition
   D. Measures the depression in freezing point

4. A car tyre of volume 0.057 m3 is inflated to 300 kPa at 300 K. After the car is driven for 10 hours, the pressure in the tyre increases to 330 kPa. Assume air is an ideal gas and Cv for air is 21 J/mole.K. The change in the internal energy of air in the tyre in J/mole is__________________?

   A. 380
   B. 630
   C. 760
   D. 880

5. A perfectly insulated container of volume V is divided into two equal halves by a partition. One side is under vacuum, while the other side has one mole of an ideal gas (with constant heat capacity) at 298 K. If the partition is broken, the final temperature of the gas in the container___________________?

   A. Will be greater than 298 K
   B. Will be 298 K
   C. Will be less than 298 K
   D. Cannot be determined

6. Assuming applicability of ideal gas law, the pure component volume of the vapor in a saturated gas can be calculated from theoretical relationship. The volumetric composition of a vapor saturated gas is independent of the___________________?

   A. Nature of the liquid
   B. Nature of the gas
   C. Temperature of the liquid
   D. Total pressure

7. According to Raoult’s law, “The vapor pressure exerted by component in a solution is proportional to the mole fraction of that component.” Raoult’s law is not applicable under the following assumption/condition?

   A. No component is concentrated at the surface of the solution
   B. The component molecules are non polar and are of almost equal size
   C. In the formation of solution, chemical combination/molecular association between unlike
   molecules takes place
   D. The attractive forces between like and unlike molecules are almost equal

8. The value of (Cp – Cv) for a real gas obeying Vander Wall’s equation is____________________?

   A. R
   B. > R
   C. < R
   D. 0.5 R

9. One kg of saturated steam at 100°C and 1.01325 bar is contained in a rigid walled vessel. It lias a volume of 1.673 m3. It cools to 98°C; the saturation pressure is 0.943 bar ; one kg of water vapour under these conditions has a volume of 1.789 m3. The latent heat of condensation (kJ/kg-1 ) under these conditions is___________________?

   A. 40732
   B. 2676
   C. 2263
   D. 540

10. Which of the following is followed by an ideal solution ?

    A. Boyle’s law
    B. Amagat’s law
    C. Raoult’s law
    D. Trouton’s rule