A. μi = (∂F/∂ni)T, P, ni
B. μi = (∂A/∂ni)T, P, ni
C. μi = (∂F/∂ni)T, P
D. μi = (∂A/∂ni)T, P
Related Mcqs:
- At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.) ?
A. μ° + RT ln f
B. μ°+ R ln f
C. μ° + T ln f
D. μ° + R/T ln f - Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance at constant temperature and pressure is________________?
A. 0
B. 1
C. ∞
D. None of these - When liquid and vapour phase of multi-component system are in equilibrium (at a given temperature and pressure), then chemical potential of each component is___________________?
A. Same in both the phases
B. Zero in both the phases
C. More in vapour phase
D. More in liquid phase - The chemical potential of a component (μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of substance added for an infinitesimal addition at constant temperature and pressure. It is given by_________________?
A. (∂E/∂ni)S, v, nj
B. (∂G/∂ni)T, P, nj = (∂A/∂ni) T, v, nj
C. (∂H/∂ni)S, P, nj
D. All (A), B. and (C) - Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and temperature ____________ as its mole fraction increases?
A. Decreases
B. Decreases exponentially
C. Increases
D. Remain constant - For a multi-component system, the term chemical potential is equivalent to the ___________________?
A. Molal concentration difference
B. Molar free energy
C. Partial molar free energy
D. Molar free energy change - For a real gas, the chemical potential is given by_____________________?
A. RT d ln P
B. RT d ln f
C. R d ln f
D. None of these - For an ideal gas, the chemical potential is given by______________?
A. RT d ln P
B. R d ln P
C. R d ln f
D. None of these - A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yi is the liquid activity coefficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of ______________________?
A. Temperature only
B. Temperature and pressure only
C. Temperature, pressure and liquid composition xi only
D. Temperature, pressure, liquid composition xi and vapour composition yi - For multi-component multiple phases to be in equilibrium at the same pressure and temperature, the _______________ of each component must be same in all phases?
A. Chemical potential
B. Fugacity
C. Both A. and B
D. Neither A. nor B
