A. (∂E/∂ni)S, v, nj
B. (∂G/∂ni)T, P, nj = (∂A/∂ni) T, v, nj
C. (∂H/∂ni)S, P, nj
D. All (A), B. and (C)
Related Mcqs:
- Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance at constant temperature and pressure is________________?
A. 0
B. 1
C. ∞
D. None of these - At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.) ?
A. μ° + RT ln f
B. μ°+ R ln f
C. μ° + T ln f
D. μ° + R/T ln f - At constant temperature and pressure, for one mole of a pure substance, the ratio of the free energy to the chemical potential is____________________?
A. Zero
B. One
C. Infinity
D. Negative - A solute distributes itself between two non-miscible solvents in contact with each other in such a way that, at a constant temperature, the ratio of its concentrations in two layers is constant, irrespective of its total amount”. This is_________________?
A. The distribution law
B. Followed from Margules equation
C. A corollary of Henry’s law
D. None of these - The vapour pressure of water is given by, in Psat = A – (5000/T), where A is a constant, Psat is the vapour pressure in atm. and T is the temperature in K. The vapor pressure of water in atm. at 50°C is approximately__________________?
A. 0.07
B. 0.09
C. 0.11
D. 0.13 - When liquid and vapour phase of multi-component system are in equilibrium (at a given temperature and pressure), then chemical potential of each component is___________________?
A. Same in both the phases
B. Zero in both the phases
C. More in vapour phase
D. More in liquid phase - The chemical potential for a pure substance is ____________ its partial molal free energy?
A. More than
B. Less than
C. Equal to
D. Not related to - The equation DU = Tds – PdV is applicable to infinitesimal changes occuring in_________________?
A. An open system of constant composition
B. A closed system of constant composition
C. An open system with changes in composition
D. A closed system with changes in composition - 1m3 of an ideal gas at 500 K and 1000 kPa expands reversibly to 5 times its initial volume in an insulated container. If the specific heat capacity (at constant pressure) of the gas is 21 J/mole . K, the final temperature will be ?
A. 35 K
B. 174 K
C. 274 K
D. 154 K - Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and temperature ____________ as its mole fraction increases?
A. Decreases
B. Decreases exponentially
C. Increases
D. Remain constant
