A. k2 CB0 > k1 CA0
B. k CA0 > k2.CB0
C. CB0 > CA0
D. CA0 > CB0
Related Mcqs:
- Second order consecutive irreversible reaction as shown in the bellow figure, were carried out in a constant volume isothermal batch reactor with different initial feed compositions. Reactor temperature was same in all the cases. In experiments where the ratio of concentration of B to that of A in the initial feed was less than 0.5, the concentration of B increased first, reached a maximum and then declined with time. However, for all experiments where this concentration ratio was 0.5 or above, concentration of B decreased monotonically with time right from the beginning. What is the ratio of the two rate constants (k1/k2) ?
A. 1/4
B. 1/2
C. 2
D. 4 - What is the order of chemical reaction as shown in the bellow figure, if it is found that the reaction rate doubles on doubling the concentration of B and also the reaction rate doubles when the concentrations of both A & B were doubled and quadrupled when the concentrations of both B & C were doubled ?
A. 1
B. 2
C. 3
D. 4 - The first order gas phase reaction as shown in the bellow figure is conducted isothermally in batch mode. The rate of change of conversion with time is given by________________?
A. dXA/dt = k1 (1 – XA)2 (1 + 2XA)
B. dXA/dt = k1 (1 – XA) (1 + 0.5XA)
C. dXA/dt = k1 (1 – XA)
D. dXA/dt = k1 (1 – XA)/(1 + XA) - Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants; but it is a function of reaction temperature. In a chemical reaction, the time required to reduce the concentration of reactant from 100 gm moles/litre to 50 gm moles/litre is same as that required to reduce it from 2 gm moles/litre to 1 gm mole/litre in the same volume. Then the order of this reaction is ?
A. 0
B. 1
C. 2
D. 3 - The following gas phase reaction is taking place in a plug flow reactor. A stoichiometric mixture of A and B at 300 K is fed to the reactor. At 1 m along the length of the reactor, the temperature is 360 K. The pressure drop is negligible and an ideal gas behaviour can be assumed. Identify the correct expression relating the concentration of A at the inlet (CA0), concentration of A at 1m (CA) and the corresponding conversion of A (X) ?
A. CA = 1.2 CA0 (1 – X)/(1 – 0.33X)
B. CA = 1.2 CA0 (1 – X)/(1 – 0.5X)
C. CA = 0.83 CA0 (1 – X)/(1 – 0.33X)
D. CA = 0.83 CA0 (1 – X)/(1 – 0.5X) - The gas phase reaction 2A ⇌ B is carried out in an isothermal plug flow reactor. The feed consists of 80 mole % A and 20 mole % inerts. If the conversion of A at the reactor exit is 50%, then CA/CA0 at the outlet of the reactor is _______________________?
A. 2/3
B. 5/8
C. 1/3
D. 3/8 - The conversion for a second order, irreversible reaction (constant volume) as shown in the bellow figure, in batch mode is given by______________?
A. 1/(1 + k2 . CA0 . t)
B. (k2 . CA0 . t)/ (1 + k2 . CA0 . t)
C. (k2 . CA0 . t)2/ (1 + k2 . CA0 . t)
D. (k2 . CA0 . t)/ (1 + k2 . CA0 . t)2 - The reaction A → B is conducted in an isothermal batch reactor. If the conversion of A increases linearly with holding time, then the order of the reaction is __________________?
A. 0
B. 1
C. 1.5
D. 2 - A CSTR is to be designed in which an exothermic liquid phase first order reaction of the type, A → R, is taking place. The reactor is to be provided with a jacket in which coolant is flowing. Following data is given: CA0= 5 kmole/m3; XA = 0.5; Feed temperature = reactor temperature = 40°C. Rate constant at 40°C = 1 min-1; (ΔH) = – 40kJ/mole; ρ = 1000kg/m3 CP = 4 J/gm.°C ; q = 10-3 m3/min (ρ and CP are same for the reactant and product streams). The amount of heat to be removed is_________________?
A. 2/3 kW
B. 1 kW
C. 5/3 kW
D. 4 kW - In a chemical reaction, represented by as shown in the bellow figure, it is observed that the (i) Rate of reaction increases by a factor of 4 on doubling the concentration of the reactant. (ii) Rate of reaction increases by a factor of 9 on trebling the concentration of the reactant. Then the rate of the reaction is proportional to(where, CA = concentration of the reactant)_____________________?
A. CA
B. CA2
C. CA3
D. CA4
