Consider the ‘n’ th order irreversible liquid phase reaction A → B. Which one of the following plots involving half life of the reaction (t1/2) and the initial reactant concentration (CA0) gives a straight line plot ?

Related Mcqs:

1. In a chemical reaction, represented by as shown in the bellow figure, it is observed that the (i) Rate of reaction increases by a factor of 4 on doubling the concentration of the reactant. (ii) Rate of reaction increases by a factor of 9 on trebling the concentration of the reactant. Then the rate of the reaction is proportional to(where, CA = concentration of the reactant)_____________________?

   A. CA
   B. CA2
   C. CA3
   D. CA4

2. Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants; but it is a function of reaction temperature. In a chemical reaction, the time required to reduce the concentration of reactant from 100 gm moles/litre to 50 gm moles/litre is same as that required to reduce it from 2 gm moles/litre to 1 gm mole/litre in the same volume. Then the order of this reaction is ?

   A. 0
   B. 1
   C. 2
   D. 3

3. Second order consecutive irreversible reaction as shown in the bellow figure, were carried out in a constant volume isothermal batch reactor with different initial feed compositions. Reactor temperature was same in all the cases. In experiments where the ratio of concentration of B to that of A in the initial feed was less than 0.5, the concentration of B increased first, reached a maximum and then declined with time. However, for all experiments where this concentration ratio was 0.5 or above, concentration of B decreased monotonically with time right from the beginning. What is the ratio of the two rate constants (k1/k2) ?

   A. 1/4
   B. 1/2
   C. 2
   D. 4

4. A CSTR is to be designed in which an exothermic liquid phase first order reaction of the type, A → R, is taking place. The reactor is to be provided with a jacket in which coolant is flowing. Following data is given: CA0= 5 kmole/m3; XA = 0.5; Feed temperature = reactor temperature = 40°C. Rate constant at 40°C = 1 min-1; (ΔH) = – 40kJ/mole; ρ = 1000kg/m3 CP = 4 J/gm.°C ; q = 10-3 m3/min (ρ and CP are same for the reactant and product streams). The amount of heat to be removed is_________________?

   A. 2/3 kW
   B. 1 kW
   C. 5/3 kW
   D. 4 kW

5. The following half life data are available for the irreversible liquid phase reaction A → products. The overall order of reaction is __________________?

   A. 0.5
   B. 1
   C. 1.5
   D. 2

6. If the time required to change the concentration of reactant to half its original value is independent of the initial concentration, the order of reaction is _______________?

   A. Zero
   B. One
   C. Two
   D. Three

7. Half-life period for a first order reaction is _____________ the initial concentration of the reactant?

   A. Directly proportional to
   B. Inversely proportional to
   C. Independent of
   D. None of these

8. A second order liquid phase reaction, A → B, is carried out in a mixed flow reactor operated in semi batch mode (no exit stream). The reactant A at concentration CAF is fed to the reactor at a volumetric flow rate of F. The volume of the reacting mixture is V and the density of the liquid mixture is constant. The mass balance for A is_______________________?

   A. d(VCA)/dt = -F (CAF – CA) – kCA2V
   B. d(VCA)/dt = F (CAF – CA) – kCA2V
   C. d(VCA)/dt = -FCA – kCA2V
   D. d(VCA)/dt = FCAF – kCA2V

9. Half life period of a chemical reaction is proportional to CA0 -1, if the reaction is of _______________ order?

   A. First
   B. Zero
   C. Second
   D. Third

10. A liquid decomposes by irreversible first order kinetics and the half life period of this reaction is 8 minutes. The time required for 75% conversion of the liquid will be ____________________ minutes?

    A. 4
    B. 8
    C. 12
    D. 16