What is the degree of freedom for a system comprising liquid water equilibrium with its vapour ?

Related Mcqs:

1. Saturated solution of benzene in water is in equilibrium with a mixture of air and vapours of benzene and water at room temperature and pressure. Mole fraction of benzene in liquid is xB and the vapour pressures of benzene and water at these conditions are pv B and pv w respectively. The partial pressure of benzene in air-vapour mixture is_________________?

   A. PvB
   B. xB.PvB
   C. (Patm – Pvw)xB
   D. xB.Patm

2. For water at 300°C, it has a vapour pressure 8592.7 kPa and fugacity 6738.9 kPa Under these conditions, one mole of water in liquid phase has a volume of 25.28 cm3 and that in vapour phase in 391.1 cm3.Fugacity of water (in kPa) at 9000 kPa will be__________________?

   A. 6738.9
   B. 6753.5
   C. 7058.3
   D. 9000

3. Degree of freedom of the system ice-water-vapour will be ________________?

   A. 0
   B. 1
   C. 2
   D. 3

4. At 60° C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An aqueous solution of methanol at 60° C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase mole fractions of methanol are 0.1686 and 0.5714 respectively. Activity co-efficient of methanol is__________________?

   A. 1.572
   B. 1.9398
   C. 3.389
   D. 4.238

5. Number of degrees of freedom for a three phase system in equilibrium comprising of three non-reacting chemical species is__________________?

   A. 2
   B. 0
   C. 1
   D. 3

6. What is the degree of freedom for two miscible (non-reacting) substances in vapor-liquid equilibrium forming an azeotrope ?

   A. 0
   B. 1
   C. 2
   D. 3

7. What is the number of degree of freedom for a system of two miscible non-reacting species in vapor-liquid equilibrium forming an azeotrope ?

   A. 0
   B. 2
   C. 1
   D. 3

8. A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yi is the liquid activity coefficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of ______________________?

   A. Temperature only
   B. Temperature and pressure only
   C. Temperature, pressure and liquid composition xi only
   D. Temperature, pressure, liquid composition xi and vapour composition yi

9. What is the number of degrees of freedom for liquid water in equilibrium with a mixture of nitrogen and water vapor ?

   A. 2
   B. 0
   C. 3
   D. 1

10. The reaction A (l) → R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The numbers of degrees of freedom are ?

    A. 1
    B. 2
    C. 3
    D. 0