Partial molar free energy of an element A in solution is same as its__________________?

Related Mcqs:

1. Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance at constant temperature and pressure is________________?

   A. 0
   B. 1
   C. ∞
   D. None of these

2. Consider the equilibrium A(g) + B(g) = AB(g). When the partial pressure of A is 10-2 atm, the partial pressure of B is 10-3 atm and the partial pressure of AB is 1 atm, the equilibrium constant ‘K’ is____________________?

   A. 10 atm-1
   B. 105 atm-1
   C. 10 (dimensionless)
   D. 105 (dimensionless)

3. The chemical potential for a pure substance is ____________ its partial molal free energy?

   A. More than
   B. Less than
   C. Equal to
   D. Not related to

4. The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1 is the activity co-efficient of component 1, is__________________?

   A. A . x22
   B. Ax1
   C. Ax2
   D. Ax12

5. When liquid and vapour phases of one component system are in equilibrium (at a given temperature and pressure), the molar free energy is__________________?

   A. More in vapour phase
   B. More in liquid phase
   C. Same in both the phases
   D. Replaced by chemical potential which is more in vapour phase

6. Specific/molar Gibbs free energy for a pure substance does not change during________________?

   A. Sublimation
   B. Vaporisation
   C. Melting
   D. Either A, B. or C.

7. Gibbs free energy (G) is represented by, G = H – TS, whereas Helmholtz free energy, A. is given by, A = E – TS. Which of the following is the Gibbs-Helmholtz equation ?

   A. [∂(G/T)/∂T] = – (H/T2)
   B. [∂(A/T)/∂T]V = – E/T2
   C. Both A. and B.
   D. Neither A. nor B.

8. The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of________________?

   A. T
   B. T and P
   C. T, P and Z
   D. T and Z

9. 80 kg of Na2SO4 (molecular weight = 142) is present in 330 kg of an aqueous solution. The solution is cooled such that. 80 kg of Na2SO4 .10H2O crystals separate out. The weight fraction of Na2SO4 in the remaining solution is_________________?

   A. 0.00
   B. 0.18
   C. 0.24
   D. 1.00

10. Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and temperature ____________ as its mole fraction increases?

    A. Decreases
    B. Decreases exponentially
    C. Increases
    D. Remain constant