Heat of reaction at constant volume is identified with _____________ change?

Related Mcqs:

1. In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at constant pressure as compared to that at constant volume is_______________?

   A. More
   B. Less
   C. Same
   D. Unpredictable; depends on the particular reaction

2. Those solutions in which there is no volume change upon mixing the components in the liquid state and which, when diluted do not undergo any heat change (i.e. heat of dilution is zero), are called ____________ solutions?

   A. Ideal
   B. Real
   C. Isotonic
   D. None of these

3. If the molar heat capacities (Cp or Cv) of the reactants and products of a chemical reaction are identical, then, with the increase in temperature, the heat of reaction will___________________?

   A. Increase
   B. Decrease
   C. Remain unaltered
   D. Increase or decrease; depends on the particular reaction

4. Specific _____________ does not change during phase change at constant temperature and pressure?

   A. Entropy
   B. Gibbs energy
   C. Internal energy
   D. Enthalpy

5. A gas at 0°C was subjected to constant pressure cooling until its volume became half the original volume. The temperature of the gas at this stage will be________________?

   A. 0°C
   B. 0°K
   C. -136.5°C
   D. -136.5°K

6. The free energy change for a chemical reaction is given by (where, K = equilibrium constant)________________?

   A. RT ln K
   B. -RT ln K
   C. -R ln K
   D. T ln K

7. The variation of heat of reaction with temperature at constant pressure is given by the ____________ law?

   A. Kelvin’s
   B. Antoine’s
   C. Kirchoff’s
   D. None of these

8. 1m3 of an ideal gas at 500 K and 1000 kPa expands reversibly to 5 times its initial volume in an insulated container. If the specific heat capacity (at constant pressure) of the gas is 21 J/mole . K, the final temperature will be ?

   A. 35 K
   B. 174 K
   C. 274 K
   D. 154 K

9. A perfectly insulated container of volume V is divided into two equal halves by a partition. One side is under vacuum, while the other side has one mole of an ideal gas (with constant heat capacity) at 298 K. If the partition is broken, the final temperature of the gas in the container___________________?

   A. Will be greater than 298 K
   B. Will be 298 K
   C. Will be less than 298 K
   D. Cannot be determined

10. Change of heat content when one mole of compound is burnt in oxygen at constant pressure is called the__________________?

    A. Calorific value
    B. Heat of reaction
    C. Heat of combustion
    D. Heat of formation