The variation of heat of reaction with temperature at constant pressure is given by the ____________ law?

Related Mcqs:

1. Variation of equilibrium pressure with temperature for any two phases of a given substances is given by the ____________ equation?

   A. Gibbs-Duhem
   B. Maxwell’s
   C. Clapeyron
   D. None of these

2. The vapour pressure of water is given by, in Psat = A – (5000/T), where A is a constant, Psat is the vapour pressure in atm. and T is the temperature in K. The vapor pressure of water in atm. at 50°C is approximately__________________?

   A. 0.07
   B. 0.09
   C. 0.11
   D. 0.13

3. In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at constant pressure as compared to that at constant volume is_______________?

   A. More
   B. Less
   C. Same
   D. Unpredictable; depends on the particular reaction

4. If the molar heat capacities (Cp or Cv) of the reactants and products of a chemical reaction are identical, then, with the increase in temperature, the heat of reaction will___________________?

   A. Increase
   B. Decrease
   C. Remain unaltered
   D. Increase or decrease; depends on the particular reaction

5. Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and temperature ____________ as its mole fraction increases?

   A. Decreases
   B. Decreases exponentially
   C. Increases
   D. Remain constant

6. A chemical reaction will occur spontaneously at constant pressure and temperature, if the free energy is________________?

   A. Zero
   B. Positive
   C. Negative
   D. None of these

7. The following heat engine produces power of 100,000 kW. The heat engine operates between 800 K and 300 K. It has a thermal efficiency equal to 50% of that of the Carnot engine for the same temperature. The rate at which heat is absorbed from the hot reservoir is____________________?

   A. 100,000 kW
   B. 160,000 kW
   C. 200,000 kW
   D. 320,000 kW

8. The chemical potential of a component (μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of substance added for an infinitesimal addition at constant temperature and pressure. It is given by_________________?

   A. (∂E/∂ni)S, v, nj
   B. (∂G/∂ni)T, P, nj = (∂A/∂ni) T, v, nj
   C. (∂H/∂ni)S, P, nj
   D. All (A), B. and (C)

9. Answer: Option B 392. Keeping the pressure constant, to double the volume of a given mass of an ideal gas at 27°C, the temperature should be raised to _____________ °C?

   A. 270
   B. 327
   C. 300
   D. 540

10. The efficiency of a Carnot heat engine operating between absolute temperatures T1 and T2 (when, T1 > T2) is given by (T1 – T2)/T1. The co-efficient of performance (C.O.P.) of a Carnot heat pump operating between T1 and T2 is given by__________________?

    A. T1/(T1-T2)
    B. T2/(T1-T2)
    C. T1/T2
    D. T2/R1