A. In standard state
B. At high pressure
C. At low temperature
D. In ideal state
Related Mcqs:
- Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and temperature ____________ as its mole fraction increases?
A. Decreases
B. Decreases exponentially
C. Increases
D. Remain constant - “The fugacity of a gas in a mixture is equal to the product of its mole fraction and its fugacity in the pure state at the total pressure of the mixture”. This is__________________?
A. The statement as per Gibbs-Helmholtz
B. Called Lewis-Randall rule
C. Henry’s law
D. None of these - Fugacity and pressure are numerically not equal for the gases__________________?
A. At low temperature and high pressure
B. At standard state
C. Both A. and B
D. In ideal state - Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ______________ with the increase of reduced temperature?
A. Decreases
B. Increases
C. Remains constant
D. Decreases logarithmically - A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yi is the liquid activity coefficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of ______________________?
A. Temperature only
B. Temperature and pressure only
C. Temperature, pressure and liquid composition xi only
D. Temperature, pressure, liquid composition xi and vapour composition yi - For water at 300°C, it has a vapour pressure 8592.7 kPa and fugacity 6738.9 kPa Under these conditions, one mole of water in liquid phase has a volume of 25.28 cm3 and that in vapour phase in 391.1 cm3.Fugacity of water (in kPa) at 9000 kPa will be__________________?
A. 6738.9
B. 6753.5
C. 7058.3
D. 9000 - Fugacity co-efficient of a substance is the ratio of its fugacity to__________________?
A. Mole fraction
B. Activity
C. Pressure
D. Activity co-efficient - At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.) ?
A. μ° + RT ln f
B. μ°+ R ln f
C. μ° + T ln f
D. μ° + R/T ln f - As pressure approaches zero, the ratio of fugacity to pressure (f/P) for a gas approaches____________________?
A. Zero
B. Unity
C. Infinity
D. An indeterminate value - The activity of an ideal gas is numerically ____________ its pressure?
A. More than
B. Less than
C. Equal to
D. Data insufficient, can’t be predicted
