A. 4
B. 16
C. 8
D. 2
Related Mcqs:
- For a gaseous phase reaction, rate of reaction is equal to K. CA . CB. If the volume of the reactor is suddenly reduced to 1/4th of its initial volume, then the rate of reaction compared to the original rate will be ______________ times?
A. 8
B. 16
C. 1/8
D. 1/16 - Rate constant for a first order reaction does not depend upon reaction time, extent of reaction and the initial concentration of reactants; but it is a function of reaction temperature. In a chemical reaction, the time required to reduce the concentration of reactant from 100 gm moles/litre to 50 gm moles/litre is same as that required to reduce it from 2 gm moles/litre to 1 gm mole/litre in the same volume. Then the order of this reaction is ?
A. 0
B. 1
C. 2
D. 3 - For a vapour phase catalytic reaction (A + B → P) which follows the Ridel mechanism and the reaction step is rate controlling, the rate of reaction is given by (reaction rate is irreversible, product also absorbs) ?
A. -rA = (k . PA . PB)/(1 + KAPA + KPPP)
B. -rA = (k . PA
2 – k1PP)/(1 + KAPA + KPPP)
C. -rA = (k . PA . PB)/(1 + KAPB + KBPB . KPPP)
D. -rA = (k . PA . PB)/(1 + KAPA) - In a chemical reaction, represented by as shown in the bellow figure, it is observed that the (i) Rate of reaction increases by a factor of 4 on doubling the concentration of the reactant. (ii) Rate of reaction increases by a factor of 9 on trebling the concentration of the reactant. Then the rate of the reaction is proportional to(where, CA = concentration of the reactant)_____________________?
A. CA
B. CA2
C. CA3
D. CA4 - A chemical reaction, A → 3B, is conducted in a constant pressure vessel. Starting with pure A, the volume of the reaction mixture increases 3 times in 6 minutes. The fractional conversion is ___________________?
A. 0.33
B. 0.5
C. 1
D. Data insufficient, can’t be predicted - The rate expression for a heterogeneous catalytic reaction is given by, – rA = K.KA PA(1 + KA.PA + KR.PR), where K is surface reaction rate constant and KA and KR are absorption equilibrium constants of A and R respectively. If KR PR >> (1 + KA PA), the apparent activation energy EA is equal to (given E is the activation energy for the reaction and ΔHR and ΔHA are the activation energies of adsorption of R and A) ?
A. E
B. E + ΔHA
C. E + ΔHA – ΔHR)
D. ΔHA + ΔHR - A liquid phase reaction is to be carried out under isothermal conditions. The reaction rate as a function of conversion has been determined experimentally and is shown in the figure given below. What choice of reactor or combination of reactors will require the minimum overall reactor volume, if a conversion of 0.9 is desired ?
A. CSTR followed by a PFR
B. PFR followed by a CSTR
C. CSTR followed by a PFR followed by a CSTR
D. PFR followed by a CSTR followed by a PFR - The rate controlling step for the heterogeneous irreversible catalytic reaction A(g) + B(g) → C(g) is the surface reaction of absorbed A with absorbed B to give adsorbed C. The rate expression for this reaction can then be written as (where, KA, KB and KC are the equilibrium constants and is the rate constant of the rate controlling step) ?
A. k KA pApB / (1 + KApA + KBpB)
B. k KAKB pApB / (1 + KApA + KBpB)
C. k KAKB pApB / (1 + KApA + KBpB + KCpC)
D. k KAKB pApB / (1 + KApA + KBpB + KCpC)2 - Second order consecutive irreversible reaction as shown in the bellow figure, were carried out in a constant volume isothermal batch reactor with different initial feed compositions. Reactor temperature was same in all the cases. In experiments where the ratio of concentration of B to that of A in the initial feed was less than 0.5, the concentration of B increased first, reached a maximum and then declined with time. However, for all experiments where this concentration ratio was 0.5 or above, concentration of B decreased monotonically with time right from the beginning. What is the ratio of the two rate constants (k1/k2) ?
A. 1/4
B. 1/2
C. 2
D. 4 - What is the value of ‘n’ if the reaction rate of the chemical reaction A → B, is proportional to CA n and it is found that the reaction rate triples, when the concentration of ‘A’ is increased 9 times ?
A. 1/2
B. 1/3
C. 1/9
D. 3
