A. Third law of thermodynamics
B. Second law of thermodynamics
C. Nernst heat theorem
D. Maxwell’s relations
Related Mcqs:
- The absolute entropy for all crystalline substances at absolute zero temperature is ____________________?
A. Zero
B. Negative
C. More than zero
D. Indeterminate - Steam undergoes isentropic expansion in a turbine from 5000 kPa and 400°C (entropy = 6.65 kJ/kg K) to 150 kPa) (entropy of saturated liquid = 1.4336 kJ/kg. K, entropy of saturated vapour = 7.2234 kJ/kg. K) The exit condition of steam is_______________?
A. Superheated vapour
B. Partially condensed vapour with quality of 0.9
C. Saturated vapour
D. Partially condensed vapour with quality of 0.1 - A solid metallic block weighing 5 kg has an initial temperature of 500°C. 40 kg of water initially at 25°C is contained in a perfectly insulated tank. The metallic block is brought into contact with water. Both of them come to equilibrium. Specific heat of block material is 0.4 kJ.kg-1. K-1. Ignoring the effect of expansion and contraction and also the heat capacity to tank, the total entropy change in kJ.kg-1, K-1 is_________________?
A. -1.87
B. 0
C. 1.26
D. 3.91 - At absolute zero temperature, the _____________ of the gas is zero?
A. Pressure
B. Volume
C. Mass
D. None of these - Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance at constant temperature and pressure is________________?
A. 0
B. 1
C. ∞
D. None of these - Absolute zero temperature signifies the ____________________?
A. Minimum temperature attainable
B. Temperature of the heat reservoir to which a Carnot engine rejects all the heat that is taken in
C. Temperature of the heat reservoir to which a Carnot engine rejects no heat
D. None of these - As the temperature is lowered towards the absolute zero, the value of the quantity (∂ΔF/∂T) approaches________________?
A. Zero
B. Unity
C. Infinity
D. None of these - As the temperature is lowered towards the absolute zero, the value of ∂(ΔF)/∂T, then approaches_______________________?
A. Unity
B. Zero
C. That of the heat of reaction
D. Infinity - Entropy of a substance remains constant during a/an ____________ change?
A. Reversible isothermal
B. Irreversible isothermal
C. Reversible adiabatic
D. None of these - The expression for entropy change, ΔS = n Cp . ln (T2/T1), is valid for the ______________ of a substance?
A. Simultaneous pressure & temperature change
B. Heating
C. Cooling
D. Both B. and C