A. Lewis-Randall
B. Margules
C. Van Laar
D. Both B. & C.
Related Mcqs:
- Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ______________ with the increase of reduced temperature?
A. Decreases
B. Increases
C. Remains constant
D. Decreases logarithmically - The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1 is the activity co-efficient of component 1, is__________________?
A. A . x22
B. Ax1
C. Ax2
D. Ax12 - The equation relating E, P, V and T which is true for all substances under all conditions is given by (∂E/∂V)T = T(∂P/∂T)H – P. This equation is called the ___________________?
A. Maxwell’s equation
B. Thermodynamic equation of state
C. Equation of state
D. Redlich-Kwong equation of state - The equation, (d loge PA/d loge xA) = (d loge PA/d loge xB) applicable to a binary solution of components. A and B in equilibrium with their vapors at constant temperature and pressure is called the _____________ equation?
A. Van Laar
B. Margules
C. Gibbs-Duhem
D. Gibbs-Duhem-Margules - To obtain integrated form of Clausius-Clapeyron equation, ln (P2/P1) = (ΔHV/R) (1/T1 – 1/T2) from the exact Clapeyron equation, it is assumed that the____________________?
A. Volume of the liquid phase is negligible compared to that of vapour phase
B. Vapour phase behaves as an ideal gas
C. Heat of vaporisation is independent of temperature
D. All A , B. & C. - Joule-Thomson co-efficient which is defined as, η = (∂T/∂P)H = 1/Cp (∂H/∂T)P, changes sign at a temperature known as inversion temperature. The value of Joule-Thomson co-efficient at inversion temperature is ___________________?
A. 0
B. ∞
C. +ve
D. -ve - Van Laar equation deals with the activity co-efficients in___________________?
A. Binary solutions
B. Ternary solutions
C. Azeotropic mixture only
D. None of these - Activity co-efficient is a measure of the____________________?
A. Departure from ideal solution behaviour
B. Departure of gas phase from ideal gas law
C. Vapour pressure of liquid
D. None of these - For an ideal gas, the activity co-efficient is_________________?
A. Directly proportional to pressure
B. Inversely proportional to pressure
C. Unity at all pressures
D. None of these - For an ideal solution, the value of activity co-efficient is______________________?
A. 0
B. 1
C. 1
