A. Departure from ideal solution behaviour
B. Departure of gas phase from ideal gas law
C. Vapour pressure of liquid
D. None of these
Related Mcqs:
- Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ______________ with the increase of reduced temperature?
A. Decreases
B. Increases
C. Remains constant
D. Decreases logarithmically - Fugacity is a measure of the____________________?
A. Escaping tendencies of the same substance in different phases of a system
B. Relative volatility of a mixture of two miscible liquids
C. Behaviour of ideal gases
D. None of these - The capacity of a spring to store energy is called the spring form co-efficient. Stiffness of a spring is measured by the____________________?
A. Ability to absorb shock
B. Capacity to store energy
C. Ratio of the wire & coil diameters
D. Load to produce unit deflection - Joule-Thomson co-efficient which is defined as, η = (∂T/∂P)H = 1/Cp (∂H/∂T)P, changes sign at a temperature known as inversion temperature. The value of Joule-Thomson co-efficient at inversion temperature is ___________________?
A. 0
B. ∞
C. +ve
D. -ve - The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1 is the activity co-efficient of component 1, is__________________?
A. A . x22
B. Ax1
C. Ax2
D. Ax12 - Which of the following equations is used for the prediction of activity co-efficient from experiments ?
A. Van Laar equation
B. Margules equation
C. Wilson’s equation
D. All A, B. and C - For an ideal gas, the activity co-efficient is_________________?
A. Directly proportional to pressure
B. Inversely proportional to pressure
C. Unity at all pressures
D. None of these - In a homogeneous solution, the activity co-efficient of a component depends upon the_________________?
A. Pressure
B. Composition
C. Temperature
D. All (A), B. and (C) - At 60° C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An aqueous solution of methanol at 60° C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase mole fractions of methanol are 0.1686 and 0.5714 respectively. Activity co-efficient of methanol is__________________?
A. 1.572
B. 1.9398
C. 3.389
D. 4.238 - For an ideal solution, the value of activity co-efficient is______________________?
A. 0
B. 1
C. 1