The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of________________?

Related Mcqs:

1. Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and temperature ____________ as its mole fraction increases?

   A. Decreases
   B. Decreases exponentially
   C. Increases
   D. Remain constant

2. A gas mixture contains 6 moles of H2 and 2 moles of N2. If the total pressure of the gaseous mixture is 4 kgf/cm2; then the partial pressure of N2 in the mixture will be _____________ kgf/cm2 ?

   A. 1
   B. 2
   C. 4
   D. 8

3. Consider the equilibrium A(g) + B(g) = AB(g). When the partial pressure of A is 10-2 atm, the partial pressure of B is 10-3 atm and the partial pressure of AB is 1 atm, the equilibrium constant ‘K’ is____________________?

   A. 10 atm-1
   B. 105 atm-1
   C. 10 (dimensionless)
   D. 105 (dimensionless)

4. Saturated solution of benzene in water is in equilibrium with a mixture of air and vapours of benzene and water at room temperature and pressure. Mole fraction of benzene in liquid is xB and the vapour pressures of benzene and water at these conditions are pv B and pv w respectively. The partial pressure of benzene in air-vapour mixture is_________________?

   A. PvB
   B. xB.PvB
   C. (Patm – Pvw)xB
   D. xB.Patm

5. Assuming applicability of ideal gas law, the pure component volume of the vapor in a saturated gas can be calculated from theoretical relationship. The volumetric composition of a vapor saturated gas is independent of the___________________?

   A. Nature of the liquid
   B. Nature of the gas
   C. Temperature of the liquid
   D. Total pressure

6. The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1 is the activity co-efficient of component 1, is__________________?

   A. A . x22
   B. Ax1
   C. Ax2
   D. Ax12

7. Pressure-enthalpy chart is useful in refrigeration. The change in internal energy of an ideal fluid used in ideal refrigeration cycle is_____________________?

   A. Positive
   B. Negative
   C. Zero
   D. Infinity

8. If the heat of solution of an ideal gas in a liquid is negative, then its solubility at a given partial pressure varies with the temperature as__________________?

   A. Solubility increases as temperature increases
   B. Solubility increases as temperature decreases
   C. Solubility is independent of temperature
   D. Solubility increases or decreases with temperature depending on the Gibbs free energy change
   of solution

9. In a mixture of benzene vapor and nitrogen gas at a total pressure of 900 mm Hg, if the absolute humidity of benzene is 0.2 kg benzene/kg nitrogen, the partial pressure of benzene in mm Hg is__________________?

   A. 180
   B. 60.3
   C. 720
   D. 200

10. Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance at constant temperature and pressure is________________?

    A. 0
    B. 1
    C. ∞
    D. None of these