A. Increases
B. Decreases
C. Remain same
D. Decreases linearly
Related Mcqs:
- Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ______________ with the increase of reduced temperature?
A. Decreases
B. Increases
C. Remains constant
D. Decreases logarithmically - Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and temperature ____________ as its mole fraction increases?
A. Decreases
B. Decreases exponentially
C. Increases
D. Remain constant - Fugacity co-efficient of a substance is the ratio of its fugacity to__________________?
A. Mole fraction
B. Activity
C. Pressure
D. Activity co-efficient - “The fugacity of a gas in a mixture is equal to the product of its mole fraction and its fugacity in the pure state at the total pressure of the mixture”. This is__________________?
A. The statement as per Gibbs-Helmholtz
B. Called Lewis-Randall rule
C. Henry’s law
D. None of these - A reasonably general expression for vapour-liquid phase equilibrium at low to moderate pressure is φi yi P = Yi xifi° where, Φ is a vapor fugacity component, Yi is the liquid activity coefficient and fi° is the fugacity of the pure component i. the Ki value (Yi = Ki xi) is therefore, in general a function of ______________________?
A. Temperature only
B. Temperature and pressure only
C. Temperature, pressure and liquid composition xi only
D. Temperature, pressure, liquid composition xi and vapour composition yi - For water at 300°C, it has a vapour pressure 8592.7 kPa and fugacity 6738.9 kPa Under these conditions, one mole of water in liquid phase has a volume of 25.28 cm3 and that in vapour phase in 391.1 cm3.Fugacity of water (in kPa) at 9000 kPa will be__________________?
A. 6738.9
B. 6753.5
C. 7058.3
D. 9000 - Joule-Thomson co-efficient which is defined as, η = (∂T/∂P)H = 1/Cp (∂H/∂T)P, changes sign at a temperature known as inversion temperature. The value of Joule-Thomson co-efficient at inversion temperature is ___________________?
A. 0
B. ∞
C. +ve
D. -ve - For a stable phase at constant pressure and temperature, the fugacity of each component in a binary system _____________ as its mole fraction increases?
A. Decreases
B. Increases
C. Remain same
D. Decreases linearly - At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.) ?
A. μ° + RT ln f
B. μ°+ R ln f
C. μ° + T ln f
D. μ° + R/T ln f - The standard state of a gas (at a given temperature) is the state in which fugacity is equal to__________________?
A. Unity
B. Activity
C. Both A. & B
D. Neither A. nor B
