The relation connecting the fugacities of various components in a solution with one another and to composition at constant temperature and pressure is called the _____________ equation?

Related Mcqs:

1. The equation, (d loge PA/d loge xA) = (d loge PA/d loge xB) applicable to a binary solution of components. A and B in equilibrium with their vapors at constant temperature and pressure is called the _____________ equation?

   A. Van Laar
   B. Margules
   C. Gibbs-Duhem
   D. Gibbs-Duhem-Margules

2. Gibbs-Duhem equation relates composition in liquid phase and the _____________ at constant temperature & pressure?

   A. Fugacity
   B. Partial pressure
   C. Activity co-efficient
   D. All (A), (B), and (C)

3. Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and temperature ____________ as its mole fraction increases?

   A. Decreases
   B. Decreases exponentially
   C. Increases
   D. Remain constant

4. The vapour pressure of water is given by, in Psat = A – (5000/T), where A is a constant, Psat is the vapour pressure in atm. and T is the temperature in K. The vapor pressure of water in atm. at 50°C is approximately__________________?

   A. 0.07
   B. 0.09
   C. 0.11
   D. 0.13

5. 80 kg of Na2SO4 (molecular weight = 142) is present in 330 kg of an aqueous solution. The solution is cooled such that. 80 kg of Na2SO4 .10H2O crystals separate out. The weight fraction of Na2SO4 in the remaining solution is_________________?

   A. 0.00
   B. 0.18
   C. 0.24
   D. 1.00

6. Critical solution temperature (or the con-solute temperature) for partially miscible liquids (e.g., phenol-water) is the minimum temperature at which___________________?

   A. A homogeneous solution (say of phenol water) is formed
   B. Mutual solubility of the two liquids shows a decreasing trend
   C. Two liquids are completely separated into two layers
   D. None of these

7. If a solution of eutectic composition is cooled, _______________ reaching the eutectic temperature ?

   A. The solvent begins to freeze out even before
   B. It will undergo no change until
   C. It will not solidify even on
   D. None of these

8. Saturated solution of benzene in water is in equilibrium with a mixture of air and vapours of benzene and water at room temperature and pressure. Mole fraction of benzene in liquid is xB and the vapour pressures of benzene and water at these conditions are pv B and pv w respectively. The partial pressure of benzene in air-vapour mixture is_________________?

   A. PvB
   B. xB.PvB
   C. (Patm – Pvw)xB
   D. xB.Patm

9. Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ______________ with the increase of reduced temperature?

   A. Decreases
   B. Increases
   C. Remains constant
   D. Decreases logarithmically

10. The partial molar enthalpy of a component in an ideal binary gas mixture of composition Z, at a temperature T and pressure P, is a function only of________________?

    A. T
    B. T and P
    C. T, P and Z
    D. T and Z