A. Lewis-Randall rule
B. Statement of Van’t Hoff Equation
C. Le-Chatelier’s principle
D. None of these
Related Mcqs:
- Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance at constant temperature and pressure is________________?
A. 0
B. 1
C. ∞
D. None of these - Two substances are in equilibrium in a reversible chemical reaction. If the concentration of each substance is doubled, then the value of the equilibrium constant will be___________________?
A. Same
B. Doubled
C. Halved
D. One fourth of its original value - What is the degree of freedom for two miscible (non-reacting) substances in vapor-liquid equilibrium forming an azeotrope ?
A. 0
B. 1
C. 2
D. 3 - Number of degrees of freedom for a three phase system in equilibrium comprising of three non-reacting chemical species is__________________?
A. 2
B. 0
C. 1
D. 3 - At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.) ?
A. μ° + RT ln f
B. μ°+ R ln f
C. μ° + T ln f
D. μ° + R/T ln f - The chemical potential of a component (μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of substance added for an infinitesimal addition at constant temperature and pressure. It is given by_________________?
A. (∂E/∂ni)S, v, nj
B. (∂G/∂ni)T, P, nj = (∂A/∂ni) T, v, nj
C. (∂H/∂ni)S, P, nj
D. All (A), B. and (C) - The chemical potential for a pure substance is ____________ its partial molal free energy?
A. More than
B. Less than
C. Equal to
D. Not related to - Entropy change of mixing two liquid substances depends upon the_________________?
A. Molar concentration
B. Quantity (i.e. number of moles)
C. Both A. and B
D. Neither A. nor B - If the molar heat capacities (Cp or Cv) of the reactants and products of a chemical reaction are identical, then, with the increase in temperature, the heat of reaction will___________________?
A. Increase
B. Decrease
C. Remain unaltered
D. Increase or decrease; depends on the particular reaction - What is the number of degree of freedom for a system of two miscible non-reacting species in vapor-liquid equilibrium forming an azeotrope ?
A. 0
B. 2
C. 1
D. 3
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