The value of Trouton’s ratio (λb/Tb) for a number of substances is 21 (where, λb = molal that of vaporisation of a substance at its normal boiling point, KCal/kg. mole and Tb = normal boiling point, °K). The Kistyakowsky equation is used for calculation of Trouton’s ratio of _____________ liquids?

Related Mcqs:

1. The accumulation in a steady state combustion process, burning 1 kg mole of carbon with 1 kg mole of oxygen thereby producing 1 kg mole of carbon dioxide, is _____________ kg mole?

   A. 1
   B. 0
   C. 16
   D. 44

2. Except for monatomic gases, the molal heat capacity at constant volume for all gases is _____________ Kcal/Kg mole.° K?

   A. 3
   B. > 3
   C. < 3
   D. < 1

3. At 100°C, water and methylcyclohexane both have vapour pressures of 1 atm. Also at 100°C, the latent heats of vaporisation of these compounds are 40.63 kJ/mole for water and 31.55 kJ/mole for methylcyclohexane. The vapour pressure of water at 150°C is 4.69 atm. At 150°C, the vapour pressure of methylcyclohexane would be expected to be_________________?

   A. Significantly less than 4.69 atm
   B. Nearly equal to 4.69 atm
   C. Significantly more than 4.69 atm
   D. Indeterminate due to lack of data

4. A fluid gas produced on burning furnace oil contains 0.15 gm mole of CO2, 0.05 gm mole of oxygen and 0.80 gm mole of N2. What is its molecular weight ?

   A. 28.6
   B. 30.0
   C. 30.6
   D. 32.6

5. The combustion equations of carbon and carbon monoxide are as follows: C + O2 = CO2, ΔH = – 394 kJ/kg .mole CO + ½ O2 = CO2, ΔH = – 284.5 kJ/kg. mole. The heat of formation of CO is _____________ kJ/kg. mole?

   A. -109.5
   B. +109.5
   C. +180
   D. +100

6. One mole of methane undergoes complete combustion in a stoichiometric amount of air. The reaction proceeds as CH4 + 2O2 → CO2 + 2H2O. Both the reactants and products are in gas phase. ΔH°298 = – 730 kJ/mole of methane. Mole fraction of water vapour in the product gases is about_____________________?

   A. 0.19
   B. 0.33
   C. 0.40
   D. 0.67

7. At standard conditions, N2 + 2O2 ⇌ 2NO2; ΔG° = 100 kJ/mole NO + ½O2 ⇌ 2NO2; ΔG° = -35 kJ/mole The standard free energy of formation of NO in kJ/mole is___________________?

   A. 15
   B. 30
   C. 85
   D. 170

8. What is the total pressure exerted by a mixture of 0.45 kg mole of benzene, 0.44 kg mole of toluene and 0.23 kg mole of o-xylene at 100°C, if their vapor pressures at 100°C are 1340, 560 and 210 mmHg respectively ?

   A. 756.2
   B. 780.5
   C. 801.5
   D. 880.5

9. A very dilute solution is prepared by dissolving ‘x1’ mole of solute in ‘x2’ mole of a solvent. The mole fraction of solute is approximately equal to_________________?

   A. x1/x2
   B. x2/x1
   C. 1 – (x1/x2)
   D. 1/x2

10. A butane isomerisation process produces 70 k.mole/hr of pure iso-butane. A purge stream removed continuously, contains 85% n-butane and 15% impurity (mole%). The feed stream is n-butane containing 1% impurity (mole%). The flow rate of the purge stream will be_________________?

    A. 3 kmole/hr
    B. 4 kmole/hr
    C. 5 kmole/hr
    D. 6 kmole/hr