A. F = A + PV
B. F = E + A
C. F = A – TS
D. F = A + TS
Related Mcqs:
- The equation relating E, P, V and T which is true for all substances under all conditions is given by (∂E/∂V)T = T(∂P/∂T)H – P. This equation is called the ___________________?
A. Maxwell’s equation
B. Thermodynamic equation of state
C. Equation of state
D. Redlich-Kwong equation of state - The equation, (d loge PA/d loge xA) = (d loge PA/d loge xB) applicable to a binary solution of components. A and B in equilibrium with their vapors at constant temperature and pressure is called the _____________ equation?
A. Van Laar
B. Margules
C. Gibbs-Duhem
D. Gibbs-Duhem-Margules - To obtain integrated form of Clausius-Clapeyron equation, ln (P2/P1) = (ΔHV/R) (1/T1 – 1/T2) from the exact Clapeyron equation, it is assumed that the____________________?
A. Volume of the liquid phase is negligible compared to that of vapour phase
B. Vapour phase behaves as an ideal gas
C. Heat of vaporisation is independent of temperature
D. All A , B. & C. - Pick out the Clausius-Clapeyron equation from the following?
A. dP/dT = ΔH/TΔV
B. ln P = – (ΔH/RT) + constant
C. ΔF = ΔH + T [∂(ΔF)/∂T]P
D. None of these - Pick out the correct statement?
A. If an insoluble gas is passed through a volatile liquid placed in a perfectly insulated container,
the temperature of the liquid will increase
B. A process is irreversible as long as Δ S for the system is greater than zero
C. The mechanical work done by a system is always equal to∫P.dV
D. The heat of formation of a compound is defined as the heat of reaction leading to the
formation of the compound from its reactants - Pick out the correct statement ?
A. Materials exhibiting high elasticity obey Hooke’s law
B. The elastic behaviour of rubber under compression is the same as its behaviour under tension
C. The damping capacity of a material is due to its plastic deformation
D. The stress required to cause plastic flow in polycrystalline material is higher as compared to
monocrystalline materials due to the presence of grains of different orientations - Pick out the correct statement?
A. Like internal energy and enthalpy, the absolute value of standard entropy for elementary substances is zero
B. Melting of ice involves increase in enthalpy and a decrease in randomness
C. The internal energy of an ideal gas depends only on its pressure
D. Maximum work is done under reversible conditions - Trouton’s ratio of ______________ liquids is calculated using Kistyakowsky equation?
A. Polar
B. Non-polar
C. Both A. & B
D. Neither A. nor B - Gibbs-Duhem equation relates composition in liquid phase and the _____________ at constant temperature & pressure?
A. Fugacity
B. Partial pressure
C. Activity co-efficient
D. All (A), (B), and (C) - Variation of equilibrium pressure with temperature for any two phases of a given substances is given by the ____________ equation?
A. Gibbs-Duhem
B. Maxwell’s
C. Clapeyron
D. None of these
