A. Loss in surface area of the active component
B. Agglomeration of metal particles caused by thermal sintering of the solid surface
C. Covering of the catalytic active sites by a foreign substance
D. All A., B. and C.
Related Mcqs:
- Effectiveness factor E. of a catalyst pellet is defined as, E = (actual rate within pore of the catalyst)/(rate if not snowed by pore diffusion), Effectiveness factor for a first order reaction is given by (where, T = Thiele modulus) ___________________?
A. tan hT/T
B. tan T/T
C. tan hT/tan T
D. None of these - A catalyst is said to be a negative catalyst, if it ___________________?
A. Retards the rate of reaction
B. Reduces the value of equilibrium constant
C. Does not initiate the reaction
D. All A., B. and C. - A spherical porous catalyst particle of radius R is subjected to reactant A which reacts to form B by a zero order surface reaction A → B. Film mass transfer resistance is negligible and pore diffusion of A is rate controlling. The effectiveness factor of the catalyst is reported as 7/8. Which of the following statement is true?
A. Inner catalyst core of radius R/8 does not participate in reaction
B. Inner catalyst core of radius R/2 does not participate in reaction
C. Inner catalyst core of radius 7R/8 does not participate in reaction
D. Effectiveness factor for a zero order reaction cannot be 7/8 as it must always be 1 - The increase in the rate of reaction with temperature is due to__________________?
A. Increase in the number of effective collisions
B. Decrease in activation energy
C. Increase in the average kinetic energy of the reacting molecules
D. None of these - Overall rate of reaction in a heterogeneous catalytic reaction depends upon the mass and energy transfer from the fluid to solid surface and its rate of reaction is usually ________________ the concentration of catalyst, if it does not entail a chain mechanism?
A. Proportional to
B. Independent of
C. Inversely proportional to
D. Proportional to the square of - The catalytic activity of enzymes is due to their capacity to lower the ______________ energy?
A. Activation
B. Potential
C. Kinetic
D. None of these - Enzymes (a protein) are catalysts found in organisms. Its efficiency of catalysing a reaction is due to its capacity to lower the activation energy of the reaction. The enzyme ptyalin used for food digestion is present in ___________________?
A. Blood
B. Saliva
C. Intestine
D. Gland - If CA is the quantity of reactants initially present, the quantity left after ‘n’ half periods will be equal to__________________?
A. (CA/2)n
B. (½)n CA
C. (CA/2)1/n
D. (CA)1/2n - Catalyst is a substance, which ________________ chemical reaction?
A. Increases the speed of a
B. Decreases the speed of a
C. Can either increase or decrease the speed of a
D. Alters the value of equilibrium constant in a reversible - Bulk diffusion in catalyst pore _______________ with increase in pressure?
A. Increases
B. Decreases
C. Remains unchanged
D. Increases exponentially