Assume that benzene is insoluble in water. The normal boiling points of benzene and water are 80.1 and 100°C respectively. At a pressure of 1 atm, the boiling point of a mixture of benzene and water is__________________?

Related Mcqs:

1. Saturated solution of benzene in water is in equilibrium with a mixture of air and vapours of benzene and water at room temperature and pressure. Mole fraction of benzene in liquid is xB and the vapour pressures of benzene and water at these conditions are pv B and pv w respectively. The partial pressure of benzene in air-vapour mixture is_________________?

   A. PvB
   B. xB.PvB
   C. (Patm – Pvw)xB
   D. xB.Patm

2. The boiling points for pure water and pure toluene are 100°C and 110.6°C respectively. Toluene and water are completely immiscible in each other. A well agitated equimolar mixture of toluene and water are prepared. The temperature at which the above mixture will exert a pressure of one standard atm. is___________________?

   A. Less than 100°C
   B. 100°C
   C. Between 100 and 110°C
   D. 110.6°C

3. In a mixture of benzene vapor and nitrogen gas at a total pressure of 900 mm Hg, if the absolute humidity of benzene is 0.2 kg benzene/kg nitrogen, the partial pressure of benzene in mm Hg is__________________?

   A. 180
   B. 60.3
   C. 720
   D. 200

4. At 100°C, water and methylcyclohexane both have vapour pressures of 1 atm. Also at 100°C, the latent heats of vaporisation of these compounds are 40.63 kJ/mole for water and 31.55 kJ/mole for methylcyclohexane. The vapour pressure of water at 150°C is 4.69 atm. At 150°C, the vapour pressure of methylcyclohexane would be expected to be_________________?

   A. Significantly less than 4.69 atm
   B. Nearly equal to 4.69 atm
   C. Significantly more than 4.69 atm
   D. Indeterminate due to lack of data

5. The vapour pressure of water is given by, in Psat = A – (5000/T), where A is a constant, Psat is the vapour pressure in atm. and T is the temperature in K. The vapor pressure of water in atm. at 50°C is approximately__________________?

   A. 0.07
   B. 0.09
   C. 0.11
   D. 0.13

6. What is the total pressure exerted by a mixture of 0.45 kg mole of benzene, 0.44 kg mole of toluene and 0.23 kg mole of o-xylene at 100°C, if their vapor pressures at 100°C are 1340, 560 and 210 mmHg respectively ?

   A. 756.2
   B. 780.5
   C. 801.5
   D. 880.5

7. The vapor pressures of benzene and toluene are 3 and 4/3 atmospheres respectively. A liquid feed of 0.4 moles of benzene and 0.6 moles of toluene is vaporised. Assuming that the products are in equilibrium, the vapor phase mole fraction of benzene is_________________?

   A. 0.4
   B. 0.6
   C. 0.8
   D. 0.2

8. A vessel of volume 1000 m3 contains air which is saturated with water vapour. The total pressure and temperature are 100 kPa and 20°C respectively. Assuming that the vapour pressure of water at 20°C is 2.34 kPa, the amount of water vapour (in kg) in the vessel is approximately ?

   A. 17
   B. 20
   C. 25
   D. 34

9. A gas mixture contains 6 moles of H2 and 2 moles of N2. If the total pressure of the gaseous mixture is 4 kgf/cm2; then the partial pressure of N2 in the mixture will be _____________ kgf/cm2 ?

   A. 1
   B. 2
   C. 4
   D. 8

10. The value of Trouton’s ratio (λb/Tb) for a number of substances is 21 (where, λb = molal that of vaporisation of a substance at its normal boiling point, KCal/kg. mole and Tb = normal boiling point, °K). The Kistyakowsky equation is used for calculation of Trouton’s ratio of _____________ liquids?

    A. Polar
    B. Non-polar
    C. Both A. & B.
    D. Neither A. nor B.