At 100°C, water and methylcyclohexane both have vapour pressures of 1 atm. Also at 100°C, the latent heats of vaporisation of these compounds are 40.63 kJ/mole for water and 31.55 kJ/mole for methylcyclohexane. The vapour pressure of water at 150°C is 4.69 atm. At 150°C, the vapour pressure of methylcyclohexane would be expected to be_________________?

Related Mcqs:

1. The vapour pressure of water is given by, in Psat = A – (5000/T), where A is a constant, Psat is the vapour pressure in atm. and T is the temperature in K. The vapor pressure of water in atm. at 50°C is approximately__________________?

   A. 0.07
   B. 0.09
   C. 0.11
   D. 0.13

2. Saturated solution of benzene in water is in equilibrium with a mixture of air and vapours of benzene and water at room temperature and pressure. Mole fraction of benzene in liquid is xB and the vapour pressures of benzene and water at these conditions are pv B and pv w respectively. The partial pressure of benzene in air-vapour mixture is_________________?

   A. PvB
   B. xB.PvB
   C. (Patm – Pvw)xB
   D. xB.Patm

3. What is the total pressure exerted by a mixture of 0.45 kg mole of benzene, 0.44 kg mole of toluene and 0.23 kg mole of o-xylene at 100°C, if their vapor pressures at 100°C are 1340, 560 and 210 mmHg respectively ?

   A. 756.2
   B. 780.5
   C. 801.5
   D. 880.5

4. A vessel of volume 1000 m3 contains air which is saturated with water vapour. The total pressure and temperature are 100 kPa and 20°C respectively. Assuming that the vapour pressure of water at 20°C is 2.34 kPa, the amount of water vapour (in kg) in the vessel is approximately ?

   A. 17
   B. 20
   C. 25
   D. 34

5. One mole of methane undergoes complete combustion in a stoichiometric amount of air. The reaction proceeds as CH4 + 2O2 → CO2 + 2H2O. Both the reactants and products are in gas phase. ΔH°298 = – 730 kJ/mole of methane. Mole fraction of water vapour in the product gases is about_____________________?

   A. 0.19
   B. 0.33
   C. 0.40
   D. 0.67

6. The heats of vaporisation of CS2, C2H5OH &H2O are 26.8, 38.6 & 40.6 KJ/kg.mole respectively. The order of decreasing inter-molecular forces in these liquids is________________?

   A. H2O > C2H5OH > CS2
   B. CS2 > C2H5OH > H2O
   C. H2O > CS2 > C2H5OH
   D. CS2 > H2O > C2H5OH

7. One kg of saturated steam at 100°C and 1.01325 bar is contained in a rigid walled vessel. It lias a volume of 1.673 m3. It cools to 98°C; the saturation pressure is 0.943 bar ; one kg of water vapour under these conditions has a volume of 1.789 m3. The latent heat of condensation (kJ/kg-1 ) under these conditions is___________________?

   A. 40732
   B. 2676
   C. 2263
   D. 540

8. The accumulation in a steady state combustion process, burning 1 kg mole of carbon with 1 kg mole of oxygen thereby producing 1 kg mole of carbon dioxide, is _____________ kg mole?

   A. 1
   B. 0
   C. 16
   D. 44

9. Assume that benzene is insoluble in water. The normal boiling points of benzene and water are 80.1 and 100°C respectively. At a pressure of 1 atm, the boiling point of a mixture of benzene and water is__________________?

   A. 80.1°C
   B. Less than 80.1°C
   C. 100°C
   D. Greater than 80.1°C but less than 100°C

10. The boiling points for pure water and pure toluene are 100°C and 110.6°C respectively. Toluene and water are completely immiscible in each other. A well agitated equimolar mixture of toluene and water are prepared. The temperature at which the above mixture will exert a pressure of one standard atm. is___________________?

    A. Less than 100°C
    B. 100°C
    C. Between 100 and 110°C
    D. 110.6°C