Equilibrium constant of a reaction varies with the____________________?

Related Mcqs:

1. In which of the following reaction equilibrium, the value of equilibrium constant Kp will be more than is Kc ?

   A. 2HI ⇌ H2 + I2
   B. N2O4 ⇌ 2NO2
   C. 2SO2 + O2 ⇌ 2SO3
   D. None of these

2. Two substances are in equilibrium in a reversible chemical reaction. If the concentration of each substance is doubled, then the value of the equilibrium constant will be___________________?

   A. Same
   B. Doubled
   C. Halved
   D. One fourth of its original value

3. The reaction A (l) → R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The numbers of degrees of freedom are ?

   A. 1
   B. 2
   C. 3
   D. 0

4. Consider the equilibrium A(g) + B(g) = AB(g). When the partial pressure of A is 10-2 atm, the partial pressure of B is 10-3 atm and the partial pressure of AB is 1 atm, the equilibrium constant ‘K’ is____________________?

   A. 10 atm-1
   B. 105 atm-1
   C. 10 (dimensionless)
   D. 105 (dimensionless)

5. ____________ explains the equilibrium constant for any chemical reaction?

   A. Henry’s law
   B. Law of mass action
   C. Hess’s law
   D. None of these

6. The equilibrium constant for a chemical reaction at two different temperatures is given by__________________?

   A. Kp2/Kp1 = – (ΔH/R) (1/T2 – 1/T1)
   B. Kp2/Kp1 = (ΔH/R) (1/T2 – 1/T1)
   C. Kp2/Kp1 = ΔH (1/T2 – 1/T1)
   D. Kp2/Kp1 = – (1/R) (1/T2 – 1/T1)

7. The free energy change for a chemical reaction is given by (where, K = equilibrium constant)________________?

   A. RT ln K
   B. -RT ln K
   C. -R ln K
   D. T ln K

8. The unit of equilibrium constant of a chemical reaction is the same as that of__________________?

   A. Molar concentration
   B. Temperature
   C. Internal energy
   D. None of these

9. In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at constant pressure as compared to that at constant volume is_______________?

   A. More
   B. Less
   C. Same
   D. Unpredictable; depends on the particular reaction

10. Solid and liquid phases of a substance are in equilibrium at the____________________?

    A. Critical temperature
    B. Melting point
    C. Freezing point
    D. Both B. and C