A chemical reaction will occur spontaneously at constant pressure and temperature, if the free energy is________________?

Related Mcqs:

1. Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance at constant temperature and pressure is________________?

   A. 0
   B. 1
   C. ∞
   D. None of these

2. At constant temperature and pressure, for one mole of a pure substance, the ratio of the free energy to the chemical potential is____________________?

   A. Zero
   B. One
   C. Infinity
   D. Negative

3. Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ______________ with the increase of reduced temperature?

   A. Decreases
   B. Increases
   C. Remains constant
   D. Decreases logarithmically

4. The free energy change for a chemical reaction is given by (where, K = equilibrium constant)________________?

   A. RT ln K
   B. -RT ln K
   C. -R ln K
   D. T ln K

5. Gibbs free energy of mixing at constant pressure and temperature is always__________________?

   A. 0
   B. ∞
   C. + ve
   D. – ve

6. Gibbs free energy at constant pressure and temperature under equilibrium conditions is___________________?

   A. ∞
   B. 0
   C. Maximum
   D. Minimum

7. Gibbs free energy of a pure fluid approaches _____________ as the pressure tends to zero at constant temperature?

   A. Infinity
   B. Minus infinity
   C. Zero
   D. None of these

8. The vapour pressure of water is given by, in Psat = A – (5000/T), where A is a constant, Psat is the vapour pressure in atm. and T is the temperature in K. The vapor pressure of water in atm. at 50°C is approximately__________________?

   A. 0.07
   B. 0.09
   C. 0.11
   D. 0.13

9. Gibbs free energy (G) is represented by, G = H – TS, whereas Helmholtz free energy, A. is given by, A = E – TS. Which of the following is the Gibbs-Helmholtz equation ?

   A. [∂(G/T)/∂T] = – (H/T2)
   B. [∂(A/T)/∂T]V = – E/T2
   C. Both A. and B.
   D. Neither A. nor B.

10. In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at constant pressure as compared to that at constant volume is_______________?

    A. More
    B. Less
    C. Same
    D. Unpredictable; depends on the particular reaction